Heat Capacities of Gases: (at constant volume and Temperature)

Matter exists due to the possession of energy and there is a close interaction between energy and matter. the matter has the capability to retain to a greater or lesser extent a certain amount of energies.

in this article, we have to look at the capabilities of the gasses to absorb various amounts of energies by the change of temperature.

the heat capacity of the gas is the amount of heat required to rais the temperature of the gas by 1°C (1 k). if the quantity of the substance is one gm, then it is called specific heat.

if the weight of the gas is one gram, then it is called specific heat.

heat capacities are denoted by C. the rise of temperature is noted from 14.5° to 15.5°C. it is measured in calories K-1mol-1 in non-SI units.

what is heat capacity formula?

you can calculate heat capacity with the following formula:

                                                                    Q=mcΔT

Heat capacity  = mass x change in temperature x specific heat

Where            Q = heat capacity ( in Jouls)

                          m = mass  ( in grams)

                           c = specific heat of the object ( in °C)

                       ΔT = change in temperature  ( °C)

The Units of Heat capacity :

in SI units the molar heat capacity is expressed as JK-1mol-1.

Types of Heat Capacities

  • Heat Capacity at constant volume (Cv)
  • Heat capacity at constant pressure (Cp)

let us try to understand the first one,

Heat capacity at constant pressure (Cp)

it is the amount of heat which is required to raise the temperature of one mole of gas by 1°C, when the volume is kept constant and the pressure is allowed to increase.

we are going to discuss only monoatomic gases at the moment. monoatomic gases have the only translational motion and the kinetic energy possessed by one mole of monoatomic gas is given by kinetic energy of possessed by one mole of monoatomic gaslet us increase the temperature of this monoatomic ideal gas by 1°C. temperature change is from T to (T+1). and its kinetic energy K` at ( T+1) °C, is increase in temperature of monoatomic ideal gas by 1 degreeSubtraction Equation  (1) from (2)E'K - Ekspecific heat at constant volume

Since R= 8.3193 JK-1 mol-1

so,                                         monoatomic gas amount of energy

 it means that if we have one mole of any monoatomic gas, then molecules will absorb the same amount of heat i.e., 3/2R, when their temperatures are increased by one kelvin.

useful information!

the monoatomic gas like He, Ne, Ar and vapors of Hg, K and other metals have Cv value of 12.48Jk-1 mol-1.

the reason is that the one mole of all the monoatomic elements have Avogadro’s number of atoms, in other words, 12.48 jouls is the demand of Avogadro’s number of atoms, when we change their temperature by 1°C (1 °K) say for He, Ne, Ar etc.

now you understand the first property of heat capacity. we try to understand the second,

Heat capacity at constant pressure (Cp)

it is the amount of heat required to raise the temperature of one mole of gas by 1°C (1K) keeping the pressure constant and the volume is allowed to increase.

it is denoted by Cp.

Actually,

When we measure Cvalue of gas then some energy is expended in the expansion of the gas and pressure-volume work is done. let us calculate the additional pressure-volume work.

the general gas equation for one mole of an ideal gas is

PV = RT  …….  (4)

suppose that by increasing the temperature by one kelvin from T to ( T+1). the volume changes from V to (V + ΔV), so

P( V+ ΔV) = R( T+1)    ……   (5)

PV+ PΔV = RT+R      ……..     (6)

substitution equation  (4) in equation (6).

RT + PΔV = RT + R

so,                                                            PΔV = R      ……..    (7)

It means that R is the contribution to the molar heat capacity due to the external work. it means that the value of the Cp should be as follows:

R is the contribution to the meat capacity

substituting the value of the general gas constant R, as 8.3143Jk-1 mol-1.

general equation for heat capacity for constant pressure

it means that for monoatomic ideal gases, the amount of heat required to raise the temperature by one kelvin for one mole along with the increase of volume so that pressure remains the same is 20.8 J.

Important conclusions for Cp and Cv:

from the expressions of Cp and Cv , two important conclusions can be drawn.

 

Cp and Cv conclusions

whatever is the atomicity of the gas, the difference remains the same.

(ii) for monoatomic gases, the ratio of two heat capacities (γ) is the same i.e., 1.666.

how to find the value of gamma in cp and cv

Polyatomic gases:

the gases which contain two or more atoms in their molecules have higher values of Cp and Cv from those of monoatomic gases. the reason is that monoatomic gases only need translational energies while polyatomic gases spend their energies for rotational and vibrational motion as well. so for polyatomic gases,Cv final valuecp final value

‘X’ is the contribution of energy for rotational and vibrational motions.

two important conclusions are,

two conclusions for cp and cv

the table gives us the Cp, Cv and γ values for various gases.

              the heat capacity of gases at 25°C (JK-1 mol-1)

Gases Cp Cv Cp Cv     γ
Argon 20.84 12.49 8.31 1.66
Helium 20.79 12.48 8.31 1.66
Mercury vapors 20.66 12.38 8.28 1.66
Iodine vapor 20.80 12.48 8.32 1.67
Chlorine 33.84 25.03 8.81 1.35
Hydrogen 28.80 20.52 8.28 1.41
Hydrogen chloride 29.12 20.82 8.30 1.41
Nitrogen 29.10 20.81 8.29 1.40
Oxygen 29.40 21.05 8.35 1.40
Carbon dioxide 37.10 28.81 8.29 1.30
Hydrogen sulfide 33.10 24.75 8.35 1.33
Nitrous oxide 32.58 25.26 8.32 1.32
Sulfur dioxide 38.10 29.32 8.88 1.30

still curious? watch this video:

Some common questions about heat capacities of various substances are given that people ask on the internet.

What is the specific heat of Air?

Specific Heat Capacities of air at 300 K are CP = 1.00 kJ/kg.K, Cv =0.718 kJ/kg.K,, and k = 1.4.

What is the specific heat of Water?

The specific heat of water is 1 calorie/gram °C = 4.186 joule/gram °C which is higher than any other common substance.

What is the specific heat of Aluminium?

The specific heat of Aluminium is  0.902=  S (J/g 0C)  &  90.2  C (J/0C) for 100 g

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